Taxicab geometry in table of higher-order elements

Nonlinear Dynamics - The paper deals with the analysis of the order of the differential equation of motion describing the dynamics of a one-port network compounded of series or parallel connections...     

Lagrangian and Hamiltonian formalisms for coupled higher-order elements: theory,modeling, simulation

Nonlinear Dynamics - In this work, the definition of the constitutive relation of a classical higher-order two-terminal element from Chua’s table is extended to the coupled element. The way...     

Complete dynamical analysis of myocardial cell exposed to magnetic flux

The heart is the essential, yet complex, component of the human cardiovascular system. In the past few decades, researchers have taken giant steps toward better understanding of the cardiac system and there have been proposed some mathematical models to describe the heart's function. In this paper, a new Fitzhugh-Nagumo neuron (FNN) model is proposed to model the electrical activity of the heart in which the effect of magnetic flux is considered. Magnetic field can greatly affect the heart's function. The dynamical analyses of the model, including quantitative assessment of the system's equilibria and its stability, phase portraits analysis, bifurcation and Lyapunov exponents analysis, and basin of attraction analysis, are carried out. In addition, a model of cardiac tissue is designed to study the electrical spatiotemporal activity of heart tissue under the electromagnetic effects. Our numerical simulations confirm that the electromagnetic excitation can change the normal rhythm of the heart. It can initiate the reentrant excitations leading to emergence of spiral seeds. This study highlights the role of electromagnetic induction in dynamical instability of the action potential duration, and thus the chaotic dynamics in the cardiac tissue.     

“Quad-band flexible magnesium zinc ferrite (MgZnFe2O4)-based double negative metamaterial for microwave applications”

This article presents vertically coupled, rectangular complementary split-ring resonator-shaped quad-band double-negative (DNG) metamaterial unit cells, that is, having both negative permittivity and permeability, which redirect negative refractive and also are not found in nature. The metamaterial is fabricated on magnesium zinc ferrite-based flexible microwave substrates, and the flexible substrates are chosen with two different concentrations of magnesium (Mg) denoted by Mg₃₀ and Mg₅₀ for 30% and 50% of Mg, which possess dielectric constants of 4.32 and 3.15 and loss tangents of 0.003 and 0.005, respectively. The proposed metamaterials are demonstrated by utilizing the CST microwave simulator, and their effective parameters are extracted according to the Nicolson-Ross-Wire method. With Mg_30, the prepared, flexible metamaterial shows measured resonances at 3.70 GHz, 7 GHz, 8.60 GHz, and 9.78 GHz, whereas with Mg₅₀ it shows the measured resonances at 4.10 GHz, 7.70 GHz, 9.33 GHz, and 10.62 GHz. Very good effective medium ratios (EMR) along with DNG properties are obtained, namely 6.5 and 5.85 for Mg₃₀ and Mg_50, respectively, with a physical dimension of 12.5 × 9.5 mm² for both of the unit cells_. Also, the electric field, magnetic field, and surface current distribution at different resonances and the polarization insensitivity at different polarization angles were observed. Thus, the designed new flexible substrate microwave materials based on DNG metamaterials are potential candidates for S-, C- and X-band applications, as well as for flexible microwave technologies.     

Extraction of uranium in caustic sludge from the production of nuclear fuel components by countercurrent dissolution and acid curing

Journal of Radioanalytical and Nuclear Chemistry - The uraniferous caustic sludge (UCS) produced in the production of uranium fuel components was hardly to leach directly, due to its very low-grade...     

Polyaromatic Profluorescent Nitroxide Probes with Enhanced Photostability

Novel profluorescent mono‐ and bis‐isoindoline nitroxides linked to napthalimide and perylene diimide structural cores are described. These nitroxide‐fluorophore probes display strongly suppressed fluorescence in comparison to their corresponding non‐radical diamagnetic methoxyamine derivatives. The perylene‐based probe possessing two isoindoline systems tethered through ethynyl linkages was shown to be the most photostable in solution, demonstrating significantly enhanced longevity over the 9,10‐bis(phenylethynyl)anthracene fluorophore used in previous profluorescent nitroxide probes.     

Redox kinetics of NiO/YSZ for chemical-looping combustion and the effect of support on reducibility

This paper explores the reaction kinetics of NiO supported on YSZ (Yttria Stabilized Zirconia) as an oxygen carrier for chemical looping combustion. Nickel particles with size less than 1 μm mixed with YSZ nano-powders are used to prepare the solid mixture, with 45% mol of NiO. Redox reactivity and oxygen carrying capacity are measured in a laboratory scale fixed bed reactor in the temperature range 500–1000 °C with different concentrations of the reactive gasses. Samples are subjected to repeated redox cycles using synthetic air (O₂+Ar) for oxidation, and H₂/H₂O/Ar mixtures for reduction. NiO/YSZ demonstrates superb cyclic regenerability starting with the 2nd cycle, with full utilization of its oxygen carrying capacity. Compared to pure nickel, pronounced improvement is achieved in the kinetics and oxygen utilization. Full reduction is achieved, and the presence of H₂O does not affect the reduction rate. Reactivity is also determined as a function of conversion. Global models of redox conversion are developed, in which surface chemistry and solid diffusion are considered. Oxidation exhibits the characteristics of a shrinking-core model with internal reactions at the Ni/NiO interface being the rate limiting step, and it is weakly temperature dependent. Reduction with H₂ generally exhibits surface chemistry limitation (adsorption-desorption), with surface product formation being the rate limiting step. YSZ significantly enhances ionic transport during oxidation and reduction. Reaction rate dependencies on conversion during the two steps suggest an optimal range for the oxygen carrying capacity of the material.     

In situ and operando electrochemistry of redox enzymes

Understanding the biocatalytic or the interfacial electron transfer processes of redox enzymes is decisive to develop high-performance biofuel cells, mimetic catalysts, bioelectrosynthesis reactors, biosensors, and bioelectronic devices. The state-of-art of redox enzyme electrochemistry lies in using in situ and operando instrumentation, in which protein electrochemistry is resourcefully coupled to or hyphenated with numerous analytical techniques. Nevertheless, there is still a lot to research about the manipulation of redox proteins in the unusual sample holding environments, and bioelectrodes engineering emerges as a key. Here, we discuss these challenges in detail, focusing on contemporary instrumentation setups.     

Synthesis,Characterization of Cr Doped TeO2 Nanostructures and its Application as EGFET pH Sensor

In the present work, Cr doped tellurium dioxide nanostructures (CTO NS)(1 wt %, 6 wt %, 8 wt % and 12 wt %) synthesized by co precipitation method and characterized by CV, UV-Visible, SEM, XRD, XPS spectroscopic analysis. Electron beam deposited thin film of CTO NS having 12 wt % of Cr exhibited EGFET-pH sensitivity of 62.03 mV/pH at 250 °C in buffer solutions of pH 6–12, linearity 0.9345, drift rate of 1.12 mV/h and deviation of 0.01145 as compared with 1 wt %, 6 wt % and 8 wt % of CTO NS.